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Isostructural Potassium and Thallium Salts of Sterically Crowded Thio- and Selenophenols: A Structural and Computational Study

โœ Scribed by Denis Bubrin; Mark Niemeyer


Book ID
102167802
Publisher
John Wiley and Sons
Year
2008
Tongue
English
Weight
216 KB
Volume
2008
Category
Article
ISSN
1434-1948

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Metal ยฑ ligand binding strength and selectivity result from antagonistic metal ยฑ ligand M ยฑ L attractions and ligand ยฑ ligand L ยฑ L repulsions. On the basis of quantum-mechanical (QM) calculations on lanthanide complexes, we show that this interplay determines the binding affinities in the gas phase