Isoquinoline Synthesis via Rhodium-Catalyzed Oxidative Cross-Coupling/Cyclization of Aryl Aldimines and Alkynes
β Scribed by Guimond, Nicolas; Fagnou, Keith
- Book ID
- 118157914
- Publisher
- American Chemical Society
- Year
- 2009
- Tongue
- English
- Weight
- 204 KB
- Volume
- 131
- Category
- Article
- ISSN
- 0002-7863
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## Abstract Isoquinolines have been synthesized from the redoxβneutral dehydrative Cο£ΏN and Cο£ΏC crossβcoupling between oximines and alkynes using a catalytic amount of (pentamethylcyclopentadiene)rhodium dichloride dimer {[RhCp\*Cl~2~]~2~} and cesium acetate (CsOAc), a process that involves __ortho_
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