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Isopiestic Measurement of the Osmotic Coefficients of Aqueous{xH2SO4+(1−x)Fe2(SO4)3}Solutions at 298.15 and 323.15 K

✍ Scribed by Mariano Velázquez-Rivera; Donald A. Palmer; Richard M. Kettler

Publisher
Springer US
Year
2006
Tongue
English
Weight
453 KB
Volume
35
Category
Article
ISSN
0095-9782

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In the mixed electrolyte solution {xK2SO4 + (1-x)MgSO4}(aq), the osmotic coefficients have been measured by the isopiestic method at the temperature 298.15 K. Scatchard's neutral-electrolyte method and Pitzer-Kim's treatment were used for the activity coefficients of the K2SO4 and MgSO4 calculation.

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The osmotic coefficients of the mixed electrolyte solution yK SO q 1 y y Mg NO aq 2 4 3 2 have been measured by the isopiestic method, at the temperature T s 298.15 K. The activity Ž . coefficients of K SO and Mg NO were calculated by Scatchard's neutral-electrolyte 2 4 3 2 method and by Pitzer and

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Isopiestic vapor-pressure measurements were made for Rb 2 SO 4 (aq) from molality m = (0.16886 to 1.5679) mol • kg -1 at T = 298.15 K and from m = (0.32902 to 1.2282) mol • kg -1 at T = 323.15 K, and for Cs 2 SO 4 (aq) from m = (0.11213 to 3.10815) mol • kg -1 at T = 298.15 K and from m = (0.11872 t