The water activities and osmotic coefficients of aqueous solutions of {(NH 4 ) 2 SO 4 + Li 2 SO 4 } and {(NH 4 ) 2 SO 4 + Na 2 SO 4 } have been determined at a temperature of 298.15 K with a hygrometric method, at molalities in the region 0.2 mol • kg -1 to saturation of the solutes for different fr
Isopiestic determination of the osmotic coefficients of Lu2(SO4)3(aq) and H2SO4(aq) at the temperatureT= 298.15 K, and review and revision of the thermodynamic properties of Lu2(SO4)3(aq) and Lu2(SO4)3·8H2O(cr)a
✍ Scribed by Joseph A. Rard
- Publisher
- Elsevier Science
- Year
- 1996
- Tongue
- English
- Weight
- 620 KB
- Volume
- 28
- Category
- Article
- ISSN
- 0021-9614
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✦ Synopsis
Isopiestic vapor-pressure measurements were made for Lu2(SO4)3(aq) at molalities from (0.35379 to 0.66478) mol•kg -1 and for H2SO4(aq) at molalities from (0.27470 to 0.70512) mol•kg -1 at the temperature T=298.15 K using KCl(aq) as the isopiestic reference standard; results for Lu2(SO4)3(aq) extend to slightly above saturation. These measurements encompass the water activity ranges aw of 0.9902EawE0.9783 and 0.9902EawE0.9741, respectively. Molality analyses used for previous solubility, density (J.
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The osmotic coefficients of the mixed electrolyte solution yK SO q 1 y y Mg NO aq 2 4 3 2 have been measured by the isopiestic method, at the temperature T s 298.15 K. The activity Ž . coefficients of K SO and Mg NO were calculated by Scatchard's neutral-electrolyte 2 4 3 2 method and by Pitzer and
In the mixed electrolyte solution {xK2SO4 + (1-x)MgSO4}(aq), the osmotic coefficients have been measured by the isopiestic method at the temperature 298.15 K. Scatchard's neutral-electrolyte method and Pitzer-Kim's treatment were used for the activity coefficients of the K2SO4 and MgSO4 calculation.