Isomers of the molecular ion of 2,3-diphenyl-1,4-benzodioxin. A comparative study with the different isomeric molecular ions of benzocyclobutenyl derivatives of 1,4-benzodioxin
✍ Scribed by Jacques Dagaut; Joëlle Fillaux; Danielle Leblanc; Pierre Dizabo
- Publisher
- John Wiley and Sons
- Year
- 1980
- Tongue
- English
- Weight
- 326 KB
- Volume
- 15
- Category
- Article
- ISSN
- 1076-5174
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✦ Synopsis
Abstract
From a study of the elimination of carbonylated radicals from 2,3‐diphenyl‐1,4‐benzodioxin and certain specifically deuterated derivatives, it has been possible to calculate the relative abundances of the different isomeric molecular ions formed. A comparison with phenylbenzocyclobutenyl derivatives of 1,4‐benzodioxin indicates that the isomerization schemes are similar.
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## Abstract Treatment of 3‐aryl‐2‐thioxo‐1,3‐thiazolidin‐4‐ones **1** with CN^−^ and NCO^−^ effected the ring cleavage providing [(cyanocarbonothioyl)amino]benzenes **4** and arylisothiocyanates **5**, respectively. Similar treatment of 5‐(2‐aryl‐2‐oxoethyl) derivatives **2** afforded 2,4‐bis(2‐ary