Isomerizations of 1,2,4-Thiadiazolidines via Thiapentalene Intermediates
✍ Scribed by Gerrit L'abbé; Nancy Weyns; Karin Buelens
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 2010
- Weight
- 104 KB
- Volume
- 99
- Category
- Article
- ISSN
- 0037-9646
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✦ Synopsis
Thiapentalenes have been postulated as hypervalent sulfur intermediates in a number of isomerizations of five-membered heterocycle^.'-^ During o u r studies on the cycloaddition-elimination reactions of 1,2,3,4-thiatriazoline-5-imines with isothiocyanates, we have discovered two consecutive isomerizations of a 1,2,4-thiadiazolidine ( 2 ) which are interpretable via thiapentalene intermedi-
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