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Isomerization via Transannular Enolate Anion

โœ Scribed by Fukunaga, Tadamichi

Book ID
126883278
Publisher
American Chemical Society
Year
1965
Tongue
English
Weight
255 KB
Volume
87
Category
Article
ISSN
0002-7863

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Stereo- and regioselective formation of
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โœ Franklin A. Davis; G. Sankar Lal; Jia Wei ๐Ÿ“‚ Article ๐Ÿ“… 1988 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 243 KB

Oxidatkn of E-and Z-vinyl lithiums with silyl peroxides 5 affords silyl enol ethers 3 in good to excellent yield with retentton of configuration. This methodobgy represents a useful new procedure for the stereoand regbselective synthesis of ketone enolates.