Isomerization of N-aryl-1-aziridinecarboximidoyl chlorides to N-(2-chloroalkyl)-N-aryl carbodiimides
β Scribed by Giacobbe, Thomas J.; Tomalia, Donald A; Sprenger, William A.
- Book ID
- 126087131
- Publisher
- American Chemical Society
- Year
- 1971
- Tongue
- English
- Weight
- 756 KB
- Volume
- 36
- Category
- Article
- ISSN
- 0022-3263
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## Abstract The reaction of ArylβN=CHβCH=NβAryl (3a: Aryl = 2,6βMe~2~C~6~H~3~; 3b: Aryl = 2,4,6βMe~3~C~6~H~2~) with 2 equiv. BCl~3~ in a toluene/hexane mixture at β50 Β°C led to an inseparable mixture of borolium salts [ArylβN^a^=CHβCH=N(Aryl)BCl~2~(__N__^__a__^β__B__)]^+^BCl~4~^β^ (4a: Aryl = 2,6βM