CO, laser and IR sources have been used to irradiate gauche CHZDCH2D isolated in a xenon matrix and the isomerization process monitored by FUR spectroscopy. Conformational interconversion has been observed, showing the unselective coupling of vibrational modes with internal rotation. The existence o
✦ LIBER ✦
Isomerization of Matrix-Isolated Formamide: IR-Spectroscopic Detection of Formimidic Acid
✍ Scribed by Günther Maier; Jörg Endres
- Publisher
- John Wiley and Sons
- Year
- 2000
- Tongue
- English
- Weight
- 167 KB
- Volume
- 2000
- Category
- Article
- ISSN
- 1434-193X
No coin nor oath required. For personal study only.
✦ Synopsis
Ultraviolet irradiation of matrix-isolated formamide (1) in solid argon with light of wavelength 248 nm leads to the formation of formimidic acid (2). Comparison of the experi-
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