Isomerization of gaseous isopentanoic acid cations: Formation of the m/z 74 ion

Dediazoniations of arenediazonium ions.

Dediazoniations of arenediazonium ions. Part 26 Influence of Substituents on the Formation of Benzoic Acids in Reactions of Aryl-Cation-Type Intermediates with CO

✍ Michael D. Ravenscroft; Peter Skrabal; Bettina Weiss; Heinrich Zollinger 📂 Article 📅 1988 🏛 John Wiley and Sons 🌐 German ⚖ 362 KB

The N2-molecule-aryl-cation pair formed as the first intermediate in dediazoniations of arenediazonium ions can be trapped with CO in H 2 0 with formation of the corresponding arenecarboxylic acids. This reaction is considered as a model for the reverse of dediazoniation, since CO is isoelectronic w