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Isomerization of allyl aryl ethers to their 1-propenyl derivatives catalysed by ruthenium complexes

✍ Scribed by Stanisław Krompiec; Nikodem Kuźnik; Robert Penczek; Józef Rzepa; Julita Mrowiec-Białoń


Book ID
108211336
Publisher
Elsevier Science
Year
2004
Tongue
English
Weight
159 KB
Volume
219
Category
Article
ISSN
1381-1169

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Highly selective synthesis of (E)-N-aryl
✍ Stanislaw Krompiec; Mariola Pigulla; Wojciech Szczepankiewicz; Tadeusz Bieg; Nik 📂 Article 📅 2001 🏛 Elsevier Science 🌐 French ⚖ 115 KB

A convenient and highly selective method of synthesis of (E)-N-aryl-N-(1-propenyl)ethanamides via isomerization of respective N-allyl-N-arylethanamides catalyzed by [RuClH(CO)(PPh 3 ) 3 ] has been described. N-Allyl-N-arylethanamides have been obtained by allylation of respective N-arylethanamides u