Isomerization of 3H- to 2H-[1]Benzothieno[3,2-b]pyrroles and Synthesis of the First Merocyanine Dyes Based on Them
โ Scribed by Alexey A. Shimkin; Valerii Z. Shirinian; Denis M. Nikalin; Mikhail M. Krayushkin; Tatiana S. Pivina; Nikolay A. Troitsky; Ludmila G. Vorontsova; Zoya A. Starikova
- Publisher
- John Wiley and Sons
- Year
- 2006
- Tongue
- English
- Weight
- 171 KB
- Volume
- 2006
- Category
- Article
- ISSN
- 1434-193X
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## Abstract 1โAlkylcyclohepta[__b__]pyrrolโ2(1__H__)โones showed rotational isomerism around the C๏ฃฟN bond. Two rotamers of the 1โ(2,4โdimethylโ3โpentyl) derivative were isolable by highโperformance liquid chromatography at 0ยฐC. The activation free energy, measured by the lineโshape analysis of the