Isomerization of 1-acetyl-4-tert-butylcyclohexanediols-1, 2
✍ Scribed by A. A. Akhrem; V. N. Dobrynin
- Book ID
- 112435493
- Publisher
- Springer
- Year
- 1967
- Tongue
- English
- Weight
- 245 KB
- Volume
- 16
- Category
- Article
- ISSN
- 1573-9171
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📜 SIMILAR VOLUMES
In the title compound, C 26 H 36 N 2 O 3 S, the amide bearing the N-S bond has an s-cis conformation, whereas that bearing the N-tert-butyl group has an s-trans conformation, the N-N-C O torsion angles being À15.1 (2) and À174.3 (2) , respectively. The steric size of the N-tert-butyl group causes th
The piperidine and cyclohexane rings in the title compound, C 19 H 25 NO 3 , are trans-fused and adopt boat and chair conformations, respectively. The phenyl and ester substituents are oriented axially with respect to the decahydroquinoline moiety. The N atom of the piperidine ring exists in a plana