Isomerization and unimolecular rearrangement channels of dithioformic acid
β Scribed by Yuanqi Tao
- Publisher
- Elsevier Science
- Year
- 1991
- Tongue
- English
- Weight
- 421 KB
- Volume
- 154
- Category
- Article
- ISSN
- 0301-0104
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
## Abstract The thermal isomerization of 1,1βdivinylcyclopropane has been investigated in the gas phase in the temperature range of 238 to 288Β°C and for pressures in the range of 4 to 12 torr. The isomerization to 1βvinylcyclopentene is homogeneous and kinetically first order and almost certainly u
Density functional theory and high-level ab initio calculations were carried out to investigate three unimolecular decomposition channels of furan. All equilibrium and transition state structures along the proposed decomposition channels are fully optimized by B3LYPr6-31G\*\* and characterized at th