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Isomerization and fragmentation of metastable tetrahydro-pyrylium ions and methyl tetrahydrofurylium ions

✍ Scribed by J.-P. Morizur; C. Monteiro; J. Tortajada


Publisher
John Wiley and Sons
Year
1987
Tongue
English
Weight
177 KB
Volume
22
Category
Article
ISSN
1076-5174

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✍ RΓΌdiger Spilker; Hans-Fr. GrΓΌtzmacher πŸ“‚ Article πŸ“… 1989 πŸ› John Wiley and Sons 🌐 English βš– 848 KB

The rearrangement of the molecular ions of the isomeric 2-and fmethyl benzofurans (1 and 2), 2H-chromene (3) and 4H-chromene (4) has been studied as a further example of the isomerization of oxygen-heteroaromatic radical cations via a ring expansionlring contraction mechanism well documented for mol