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Isomerism in the Direct Chlorination of 2-Methylpyrazine 1a

โœ Scribed by Lutz, Wilson B.; Lazarus, Sam; Klutchko, Sylvester; Meltzer, Robert I.

Book ID
127123676
Publisher
American Chemical Society
Year
1964
Tongue
English
Weight
568 KB
Volume
29
Category
Article
ISSN
0022-3263

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โœ Albert J. Fry; William B. Farnham ๐Ÿ“‚ Article ๐Ÿ“… 1968 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 200 KB

It has been demonstrated that in hydrochlorination of I-methylnorbornene, protonation takes place unselectively at both ends of the double bond (1, 2). The absence of a directive effect by the I-methyl substituent in a reaction possessed of carbonium ion character (3) was interpreted as evidence aga