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Isomerisierung der Bis(triphenylphosphin)platin(0)-Komplexe von Bicyclo[4.2.1]non-1-en und Bicyclo[4.2.1]non-1(8)-en

✍ Scribed by Erich Stamm; Konrad B. Becker; Peter Engel; Reinhart Keese

Publisher
John Wiley and Sons
Year
1979
Tongue
German
Weight
312 KB
Volume
62
Category
Article
ISSN
0018-019X

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✦ Synopsis

Isomerization of the Bis(triphenylphosphine)platin(0) Complexes of Bicyclo[4.2.1]non‐1‐ene and Bicyclo[4.2.1]non‐1(8)‐ene

Isomrisation of the Bredt‐Olefins 3 and 7 as the bis (triphenylphosphine)‐Pt(0) complexes 1 and 8, respectively, has been observed. The bridgehead‐olefin 3 as well as the bicyclic olefins 4, 5 and 6 have also been isomerized with catalytical amounts of (ethylene)bis(triphenylphosphine)platinum(0) (2).

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