Isomerisation on the CrCp2/SiO2 catalyst during polymerisation of ethylene: pressure dependence
β Scribed by Richard Blom; Ivar M. Dahl; Arild Follestad; Klaus J. Jens
- Publisher
- Elsevier Science
- Year
- 1999
- Tongue
- English
- Weight
- 109 KB
- Volume
- 138
- Category
- Article
- ISSN
- 1381-1169
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## Abstract In this work, ethylene was polymerized by using Cp~2~ZrCl~2~ supported on silica pretreated with methylaluminoxane (MAO) as the catalyst system. The influence of the conditions for the preparation of the heterogeneous catalyst, such as temperature, washing method of the catalytic solid,
The hydrogen pressure dependence of the ring-opening reactions of propylcyclobutane was studied at three different temperatures over \(\mathrm{Pt} / \mathrm{SiO}_{2}\) catalyst. At 373 and \(573 \mathrm{~K}\), only hydrogenative ring opening occurs, while appreciable amounts of aromatics, ring enlar