Isomer effects on vibrational energy relaxation in perylene-argon complexes

Coriolis effects on “intermediate case”

Coriolis effects on “intermediate case” of intramolecular vibrational relaxation: Rotational-temperature dependence of energy- resolved fluorescence from jet-cooled perylene with 776–975 cm−1 excess energies

✍ B.E. Forch; K.T. Chen; E.C. Lim 📂 Article 📅 1983 🏛 Elsevier Science 🌐 English ⚖ 362 KB

The rotational-temperature dependence of the energy-resolved fluorescence, combined with the calculated level density, indicates that the large variations in the rate of the intramolecular vibrational relaxation over a small escess energy in Sr pcrylene is due to the fluctuations in the density of a