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Isolierung der (E)-Enole von β-Ketocarbonsäurederivaten

✍ Scribed by Prof. Dr. Herbert Meier; Wolfgang Lauer; Dr. Friedrich Ulrich Scholter

Book ID
101520386
Publisher
John Wiley and Sons
Year
1985
Tongue
English
Weight
206 KB
Volume
97
Category
Article
ISSN
0044-8249

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✍ Buß, Monika ;Mayer, Axel ;Müller, Klaus ;Meier, Herbert 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 757 KB

(__Z__) and (__E__) Enols of Diaryl‐Substituted β‐Ketocarboxylic Acid Derivatives Thermolysis of the 1,3‐diaryl‐2‐diazo‐1,3‐propanediones 4 in the presence of alcohols or amines yielded the compounds 7–11 which exist as chelated (__Z__) enols or as tautomeric ketones. Contrary to the steric interac