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Isolation of pentamethylcyclopentadienylchromium tricarbonyl dimer by two methods. X-Ray crystal structural study of two polymorphs

✍ Scribed by Lai Yoong Goh; Trevor W. Hambley; Donald J. Darensbourg; Joseph Reibenspies


Publisher
Elsevier Science
Year
1990
Tongue
English
Weight
614 KB
Volume
381
Category
Article
ISSN
0022-328X

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Thallium monosulfidΓ© is a mixed valence compound, as represented by the formula \(\mathbf{T l}^{1} \mathrm{~T}^{1 \prime \prime} \mathrm{S}_{2}\). Two different structures with tetragonal symmetry are identified in TIS. The first is space group \(14 / \mathrm{mcm}: a=b=7.785(2), c=6.802(2) \AA\), an