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Isolation of New Disilanylene-bridged Bis(cyclopentadienyl)-tetracarbonyldiiron Complexes and Molecular Structure of [η5,η5-C5H4SiMe(SiMePh2)C5H4]Fe2(CO)2(μ-CO)2

✍ Scribed by Huai-Lin Sun; Hui-Li Zhang; Zhen-Sheng Zhang

Publisher
John Wiley and Sons
Year
2006
Tongue
English
Weight
70 KB
Volume
24
Category
Article
ISSN
0256-7660

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## Abstract The preparation of a family of dinuclear monocyclopentadienyl imidoniobium and ‐tantalum complexes was achieved by two different synthetic routes. The diimido complexes [{M(Cp′)Cl~2~}~2~(μ‐1,__i__‐NC~6~H~4~N)] [Cp′ = η^5^‐C~5~H~4~SiMe~3~, M = Nb, __i__ = 4 (1); Cp′ = η^5^‐C~5~H~4~SiMe~3