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Isolation of N -(2-Methyl-3-oxodecanoyl)pyrrole and N -(2-Methyl-3-oxodec-8-enoyl)pyrrole, Two New Natural Products from Penicillium brevicompactum , and Synthesis of Analogues with Insecticidal and Fungicidal Activity

✍ Scribed by Cantín, Ángel; Moya, Pilar; Miranda, Miguel A.; Primo, Jaime; Primo-Yúfera, Eduardo

Book ID: 125532799
Publisher: American Chemical Society
Year: 1998
Tongue: English
Weight: 195 KB
Volume: 46
Category: Article
ISSN: 0021-8561
DOI: 10.1021/jf9800763

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Isolation and Synthesis of N-(2-Methyl-3-oxodec-8-enoyl)-2-pyrroline and 2-(Hept-5-enyl)-3-methyl-4-oxo-6,7,8,8a-tetrahydro-4H-pyrrolo[2,1-b]1,3-oxazine – Two New Fungal Metabolites with in vivo Anti-Juvenile-Hormone and Insecticidal Activity

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Two new natural products, N- (2-methyl-3-oxodec-8-enoyl)corresponding acid chloride, in order to acylate Meldrum's acid. Subsequent aminolysis with pyrrolidine, followed by 2-pyrroline (2) and 2-(hept-5-enyl)-3-methyl-4-oxo-6,7,8,8atetrahydro-4H-pyrrolo[2,1-b]-1,3-oxazine (3), have been methylation