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Isolation of alkali and alkaline earth metal complexes by diethylene glycol dibenzoate

✍ Scribed by Deepti Mishra; Uma Sharma


Book ID
112922012
Publisher
Indian Academy of Sciences,Royal Society of Chemistry
Year
1996
Tongue
English
Weight
167 KB
Volume
108
Category
Article
ISSN
0253-4134

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## Abstract Compound [(dph‐BIAN)Mg(THF)]~2~ (**2**) was prepared by reacting magnesium metal with 1,2‐bis[(2‐biphenyl)imino]acenaphthene (dph‐BIAN) in THF, followed by crystallization from toluene. Reaction of CaI~2~ with (dpp‐BIAN)Li~2~ in toluene afforded [(dpp‐BIAN)Li]~2~Ca (**3**) (dpp‐BIAN = 1

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## Abstract Compound [(dph‐BIAN)Mg(THF)]~2~(**2**) was prepared by reacting magnesium metal with 1,2‐ bis[(2‐biphenyl)imino]acenaphthene (dph‐BIAN) in THF, followed by crystallization from toluene. Reac‐ tion of CaI~2~ with (dpp‐BIAN)Li~2~ in toluene afforded [(dpp‐BIAN)Li]~2~Ca (**3**) (dpp‐BIAN =