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Isolation of a tungsten side-bound ketone complex containing eight new carbon-carbon bonds: an alkyne-alkyne, alkyne-carbonyl and alkyne-pentamethylcyclopentadiene coupling reaction

✍ Scribed by Chetcuti, Michael J.; Grant, Brian E.; Fanwick, Phillip E.

Book ID: 126986625
Publisher: American Chemical Society
Year: 1989
Tongue: English
Weight: 315 KB
Volume: 111
Category: Article
ISSN: 0002-7863
DOI: 10.1021/ja00189a073

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Reactions of dinuclear metal carbonyl .alpha.-diimine complexes with alkynes. Part 2. Selective coupling of an .alpha.-diimine ligand and CO and methyl propynoate molecules to give Fe2(CO)n{(R)N:C(H)C(H)N(R)C(O)C(H):CC(O)OMe}, containing a flyover-type ligand and showing a reversible CO-induced metal-metal bond fission with x-ray crystal structures (n = 5, R = i-Pr; n = 6, R = c-hex)

✍ Muller, Fred.; Van Koten, Gerard.; Vrieze, Kees.; Heijdenrijk, Dick. 📂 Article 📅 1989 🏛 American Chemical Society 🌐 English ⚖ 993 KB