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Isolation of a triborylmethide salt

✍ Scribed by Matteson, Donald S.; Hagelee, Leon A.; Wilcsek, Robert J.


Book ID
127002466
Publisher
American Chemical Society
Year
1973
Tongue
English
Weight
269 KB
Volume
95
Category
Article
ISSN
0002-7863

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THE synthesis of a number of carbon free radicals possessing extraordinarily high inertness has been announced recently,i a most remarkable example being the perchlorotriphenylmethyl (PTM) radical (I). Such unusual behavior is ascribed to essentially complete steric shielding of the normally reactiv