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Isolation of a Cubane-Type Metal Sulfido Cluster with a Molecular Nitrogen Ligand

โœ Scribed by Hiroyuki Mori; Hidetake Seino; Masanobu Hidai; Yasushi Mizobe


Book ID
101562498
Publisher
John Wiley and Sons
Year
2007
Tongue
English
Weight
130 KB
Volume
46
Category
Article
ISSN
0044-8249

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Isolation of a New Cs-Symmetrized Mo3(ฮผ3
โœ Rita Hernandez-Molina; Javier Gonzalez-Platas; Cristian Vicent ๐Ÿ“‚ Article ๐Ÿ“… 2012 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 602 KB

A new cluster of formula {[Mo 3 (ฮผ 3 -S)(ฮผ-S)(ฮผ-S 2 ) 2 (dtp) 3 (ฮผ-OAc)][Mo 3 NiS 4 (dtp) 3 (ฮผ-OAc)(CH 3 CN)]} (1; dtp = diethyl dithiophosphate; OAc = acetate) comprising the novel C s -symmetrized Mo 3 (ฮผ 3 -S)(ฮผ-S)(ฮผ-S 2 ) 2 structural type covalently attached to a cubane-type Mo 3 NiS 4 core has