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Isolation and X-ray Crystal Structures of Triarylphosphine Radical Cations

✍ Scribed by Pan, Xiaobo; Chen, Xiaoyu; Li, Tao; Li, Yizhi; Wang, Xinping


Book ID
119945809
Publisher
American Chemical Society
Year
2013
Tongue
English
Weight
539 KB
Volume
135
Category
Article
ISSN
0002-7863

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## Abstract The crystal structure of the Sb~2~F~11~ salt of the 2‐phenyladamant‐2‐yl cation, 1 Β· Sb~2~F~11~, was determined at 183 K (__P__2~1~/__c__, __R__1 = 0.0652, Οƒ(Cο£ΏC) = 0.02 Γ…), because earlier published results indicated a charge delocalization from the cationic C(2) into the Οƒ framework (