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Isolation and the structure of methyl homodaphniphyllate, a plausible intermediate between daphniphylline and yuzurimine

โœ Scribed by Masaaki Toda; Shosuke Yamamura; Yoshimasa Hirata


Book ID
104239900
Publisher
Elsevier Science
Year
1969
Tongue
French
Weight
99 KB
Volume
10
Category
Article
ISSN
0040-4039

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2,5-dialkyl pyrroles react in protic media with dichlorocarbene generated under basic conditions giving rise to ring expansion products (2,6-dialkyl-3chloropyridines) and addition products (2,5-dialkyl-2-dichloromethyl-2H-pyrl roles or Plancher's pyrrolenines) . The latter are not intermediates for