Isolation and Structure Elucidation of Enniatins L, M1, M2, and N: Novel Hydroxy Analogs
✍ Scribed by Pornrapee Vongvilai; Masahiko Isaka; Prasat Kittakoop; Prasert Srikitikulchai; Palangpon Kongsaeree; Samran Prabpai; Yodhathai Thebtaranonth
- Publisher
- John Wiley and Sons
- Year
- 2004
- Tongue
- German
- Weight
- 203 KB
- Volume
- 87
- Category
- Article
- ISSN
- 0018-019X
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✦ Synopsis
Abstract
Four new cyclohexadepsipeptides, enniatins L (1), M~1~ (2), M~2~ (3), and N (4), have been isolated from an unidentified fungus (BCC 2629), together with the known enniatins B (5), H (6), and I (7), MK1688 (8), and enniatin B~4~ (9). Compounds 1–4 are the first enniatin analogs with an OH group at the side chain of one of the 2‐hydroxycarboxylic acid residues. The structures of 1–4 were elucidated by spectroscopic means and by X‐ray crystallography.
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