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Isolation and Partial Identification of Lactones from Technical Isostearic Acid

✍ Scribed by Laane, N. C. M. ;Haase, K. D. ;Ward, J. P.


Publisher
John Wiley and Sons
Year
1991
Weight
600 KB
Volume
93
Category
Article
ISSN
0931-5985

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✦ Synopsis


Using the techniques of clathrate formation with urea and chromatographic separation on silicagel, lactone fractions (about 6-80/0) were isolated from technical isostearic acid. The lactones were partially identified (GC/ MS) as a range of y-lactones which included branched and unbranched isomers and homologs, besides other compounds. A mechanism is proposed for the formation of these lactones, relating them to the bulk of the isostearic acid isomers


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