Isolation and Molecular Structure of a Monomeric, Tris[peroxotitanium(IV)]-Substituted α-Dawson Polyoxometalate Derived from the Tetrameric Anhydride Form Composed of Four Tris[titanium(IV)]-Substituted α-Dawson Substructures and Four Bridging Titanium(IV) Octahedral Groups.

Isolation and Molecular Structure of a M

Isolation and Molecular Structure of a Monomeric, Tris[peroxotitanium(IV)]-Substituted α-Dawson Polyoxometalate Derived from the Tetrameric Anhydride Form Composed of Four Tris[titanium(IV)]-Substituted α-Dawson Substructures and Four Bridging Titanium(IV) Octahedral Groups

✍ Yoshitaka Sakai; Yuh Kitakoga; Kunihiko Hayashi; Kenji Yoza; Kenji Nomiya 📂 Article 📅 2004 🏛 John Wiley and Sons 🌐 English ⚖ 192 KB

## Abstract The isolation and structural characterisation of a novel tris[peroxotitanium(IV)]‐substituted α‐Dawson polyoxometalate (POM), [α‐1,2,3‐P~2~W~15~(TiO~2~)~3~O~56~(OH)~3~]^9−^ (1a), containing side‐on coordination (i.e. η^2^‐coordination) of the peroxo group to the titanium(IV) atom are de