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Isolation and characterization of a stable 1,2-oxathietan 2-oxide (?-sultine)

✍ Scribed by Durst, Tony; Gimbarzevsky, Boris P.

Book ID
127383247
Publisher
The Royal Society of Chemistry
Year
1975
Tongue
English
Weight
144 KB
Volume
17
Category
Article
ISSN
0022-4936

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The products of hetero-Diels Β± Alder reactions (sultines) and cheletropic addition reactions (sulfolenes) between 1,3-dienes and sulfur dioxide can be distinguished by their 17 O NMR shifts. Experimental data have been collected for derivatives of 3,6dihydro-1,2-oxathiin-2-oxide and of 2,5dihydrothi