Is the formation of 1,10-phenanthroline di-N-oxide possible?

✍ Scribed by Róża Antkowiak; Wieslaw Z. Antkowiak

• Book ID: 104256584
• Publisher: Elsevier Science
• Year: 1997
• Tongue: French
• Weight: 114 KB
• Volume: 38
• Category: Article
• ISSN: 0040-4039
• DOI: 10.1016/s0040-4039(97)00212-8

✦ Synopsis

5,

was found as an additional product of the hypochlorous acid action on l,lO-phenanthroline.

When treated with MCPBA the product of the chlorine addition yielded a corresponding di-N-oxide 3, which readily lost hydrogen chloride under the influence of sadiron isopropoxide. The resulting monochloro di-N-oxide $ molecules (assumed to be flaO revealed a satisfactory stability unless the neutral or basic solution was nmde acidic.