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Is the extra stability of alkoxy anions a result of a coiling effect or of intramolecular hydrogen bonding?

✍ Scribed by J. Catalán

Publisher
Elsevier Science
Year
1994
Tongue
English
Weight
248 KB
Volume
221
Category
Article
ISSN
0009-2614

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✦ Synopsis

The coiling effect should not be invoked to account for the fact that the basicity of alkyl-amines and acidity of alkanols in the gas phase do not fall off as the chain length increases. For alkanols, the reason lies in the formation of an intramolecular hydrogen bond between a C-H group and the oxygen atom in the anion.

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