𝔖 Bobbio Scriptorium
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Irreversible deactivation of fcc catalysts

✍ Scribed by D.J. Rawlence; K. Gosling


Book ID
103935444
Publisher
Elsevier Science
Year
1991
Tongue
English
Weight
722 KB
Volume
11
Category
Article
ISSN
0920-5861

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✦ Synopsis


Controlled catalyst deactivation in the laboratory is an essential component in the sequence of tests required for the prediaion of catalyst performance in a commercial FCC unit. Conventional single and multiple point deactivation followed by MAT testing gives useful predictions of nlative catalyst activitk and trends in major yields. These predictions can be cnhancedhymathunatical~baseduponaponlmitrlsta,butcxtcnsionsinto predicting the yields of individual components within the gasoline and LPG eactions ale unreliable.Ananalvsisofthenatureoftheworkingequilibriumcasalystshowsthatitisa complex mixture of age, activity, and metals di&butions which wo& together to generate the final product spcctmm. To get closer to predkt& this spccmuq it is necessary to simulate an equilibrium catalyst by blending fresh catalyst and a series of mildly and progressively more severely deactivated catalyst samples. The appmpk@ composition of the blend can be calculated and is a function of the initial catalyst activity, the catalyst decay rates in the laboratory and PCC unit, and the targecd unit catalyst activity and make-up rate. Another major factor in laboratory scale testing lies in the natme of the catalytic testing equipment. Analysis of an FCC riser cracker in terms of catalyst, fedstock, and product . .

contacttimcsindicatesthatthefhnvcharsctenstlcs #lfCCNCidtOgsaentinsthCObSCrVCd pOdUCt-ioascradSll~thet,foraccuraCy,SlMllscale~~tMtiIlgmustbC carried out in a riser system.


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A one-parameter model of catalyst deactivation, based on the distribution of acid site strengths, is proposed. The model describes the deactivation rate as a function of time-on-stream (TOS) and accounts for the very fast initial rate of decay observed in commercial FCC. All of the model parameters