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Iron(VI) and Iron(V) Oxidation of Copper(I) Cyanide

✍ Scribed by Sharma, Virender K.; Burnett, Christopher R.; Yngard, Ria A.; Cabelli, Diane E.

Book ID
120010391
Publisher
American Chemical Society
Year
2005
Tongue
English
Weight
136 KB
Volume
39
Category
Article
ISSN
0013-936X

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The effects of oxidant, pH and ligands on iron- and copper-catalyzed ascorbate oxidation have been examined. The formation of the catalyst-substrate complex is affected by pH, whereas oxidant affects its breakdown. With copper-ion catalysis, ligands inhibit competitively. With iron catalysis, on the