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Iron—sulfur cluster micelle as a ferredoxin model

✍ Scribed by Iwao Tabushi; Yasuhisa Kuroda; Yoro Sasaki

No coin nor oath required. For personal study only.

✦ Synopsis

Iron-sulfur clusters having hydrophilic and hydrophobic L-cysteine derivative as their components were prepared.

Electronic and CD spectra of these clusters as well as their oxidation-reduction potentials are very similar to those of native enzymes.

These clusters incorporated in the micelles show satisfactory stability and electron transfer ability.

After Helm's successful preparation of the first artificial iron-sulfer clusterl), a variety of artificial iron sulfur clusters have been prepared to

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