Iron(III)−Salen Complexes as Enzyme Models: Mechanistic Study of Oxo(salen)iron Complexes Oxygenation of Organic Sulfides
✍ Scribed by Sivasubramanian, Veluchamy Kamaraj; Ganesan, Muniyandi; Rajagopal, Seenivasan; Ramaraj, Ramasamy
- Book ID
- 120821030
- Publisher
- American Chemical Society
- Year
- 2002
- Tongue
- English
- Weight
- 107 KB
- Volume
- 67
- Category
- Article
- ISSN
- 0022-3263
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The metal-salen complexes (metal = Mn, Cr, Fe, Ru, Co, V and Ti) find widespread use as efficient catalysts for the selective oxygenation of organic sulfides, sulfoxides and aromatic amines. The active oxidant can be generated from the metal-salen ion using PhIO, H 2 O 2 , t-BuO 2 H and ClO -as the
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