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Iron(III) complexation with 2,4,5-trihydroxypyrimidine

โœ Scribed by Katyal, Mohan ;Kundra, S. K. ;Singh, R. P.


Publisher
Springer-Verlag
Year
1974
Weight
232 KB
Volume
62
Category
Article
ISSN
0344-838X

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Iron(lll) hexacyanoferrate(lll) is shown to be a useful reagent in oxidative coupling of 4,5,5,. Dimerisation proceeds via oxidative demethylation and loss of chloride to give an orrho-quinonoid dimer in high yield. The proposed structure 1 is based largely on mass-spectra of methyl derivatives of t