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Iron(II) and Zinc(II) Complexes with Designed pybox Ligand for Asymmetric Aqueous Mukaiyama-Aldol Reactions.

✍ Scribed by Joanna Jankowska; Joanna Paradowska; Bartosz Rakiel; Jacek Mlynarski


Publisher
John Wiley and Sons
Year
2007
Weight
40 KB
Volume
38
Category
Article
ISSN
0931-7597

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✦ Synopsis


Abstract

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✍ Birgit Hommerich; Hendrik Schwöppe; Dirk Volkmer; Bernt Krebs 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 German ⚖ 163 KB 👁 2 views

The dinuclear nickel(II) complex of the asymmetric ligand 1-[N,N-bis(2-pyridylmethyl)amino]-3-[2-(3,5dimethyl-1H-pyrazol-1-yl)ethoxy]-2-hydroxypropane (HL1) was prepared as a model for the active site of urease. The novel complex [Ni 2 (L1)(MeCOO)(ClO 4 )(EtOH) 2 ](ClO 4 ) 0.5 Et 2 O (1) crystallize