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Iron tricarbonyl complexes of 1(1H),2-diazepine and methyl substituted derivatives. Novel fluxional organometallic compounds

✍ Scribed by Carty, A. J.; Hobson, R. F.; Patel, H. A.; Snieckus, V.


Book ID
126959375
Publisher
American Chemical Society
Year
1973
Tongue
English
Weight
365 KB
Volume
95
Category
Article
ISSN
0002-7863

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Ironcarbonyl Complexes of 5,6-Dimethylid
✍ Edia Bonfantini; Jean-Luc MΓ©tral; Pierre Vogel πŸ“‚ Article πŸ“… 1987 πŸ› John Wiley and Sons 🌐 German βš– 578 KB

The I-dimethoxymethyl-5,6-dimethylidene-7-oxabicyclo[2.2. I jhept-2-ene (9) has been prepared. On treatment with Fe,(CO),, the endocyclic double bond C(2)=C(3) was coordinated first giving the Corresponding exo-Fe(C0)4 complex 10. The latter reacted with Fe,(CO), and afforded cis-heptacarbonyl-p -[(