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Iron Porphyrins Catalyze the Synthesis of Non-Protected Amino Acid Ester from Ammonia and Diazoacetates.

โœ Scribed by Iris Aviv; Zeev Gross


Publisher
John Wiley and Sons
Year
2007
Weight
23 KB
Volume
38
Category
Article
ISSN
0931-7597

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Papain catalyzed synthesis of glyceryl e
โœ Yuri V. Mitin; Karin Braun; Peter Kuhl ๐Ÿ“‚ Article ๐Ÿ“… 1997 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 113 KB ๐Ÿ‘ 2 views

Papain catalyzed synthesis of glyceryl esters of BOC(Z)-protected amino acids and peptides was performed at 40-50ยฐC in a 50 molar excess of glycerol. Equilibrium was achieved in 6-7 h. The maximal yield of esters (50-70%) was obtained at 10% of water and pH 3.2-3.4. A lower water concentration resul