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Iron Porphyrin-Catalyzed Reduction of CO 2 . Photochemical and Radiation Chemical Studies

✍ Scribed by Grodkowski, J.; Behar, D.; Neta, P.; Hambright, P.


Book ID
126417092
Publisher
American Chemical Society
Year
1997
Tongue
English
Weight
148 KB
Volume
101
Category
Article
ISSN
1089-5639

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Minimum-energy structures of O , CO, and NO iron᎐porphyrin FeP 2 complexes, computed with the Car᎐Parrinello molecular dynamics, agree well with the available experimental data for synthetic heme models. The diatomic molecule induces a ˚Ž . 0.3᎐0.4 A displacement of the Fe atom out of the porphyrin