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Iron Polyoxometalate Single-Molecule Magnets

✍ Scribed by Jean-Daniel Compain; Pierre Mialane; Anne Dolbecq; Israël Martyr Mbomekallé; Jérôme Marrot; Francis Sécheresse; Eric Rivière; Guillaume Rogez; Wolfgang Wernsdorfer

Publisher
John Wiley and Sons
Year
2009
Tongue
English
Weight
493 KB
Volume
48
Category
Article
ISSN
0044-8249

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## Abstract **Wolframate mit Eisenfüllung**: Zwei neue Polyoxowolframate mit paramagnetischen Eisen(III)‐Ionen (siehe Struktur, W blau, Fe gelb, O rot) haben Grundzustände mit __S__=15/2 und __S__=5. Beide Verbindungen sind Einzelmolekülmagnete, und die Hexaeisen‐Spezies zeigt eine starke Hysterese

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Polyoxometalates (POMs), anionic oxide clusters of the early transition metals, [1] represent a vast class of inorganic materials with a virtually unmatched range of properties applicable to biology, [2] magnetism, [3] materials science, [4] or catalysis. [5] This unique span of properties qualifies