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Iron cyclopentadienyldicarbonyl complexes with azoles. II. Iron cyclopentadienyl complexes with vicinal triazoles

✍ Scribed by A.N. Nesmeyanov; Yu.A. Belousov; V.N. Babin; N.S. Kochetkova; S.Yu. Sil'vestrova; E.I. Mysov

Publisher
Elsevier Science
Year
1977
Tongue
English
Weight
647 KB
Volume
23
Category
Article
ISSN
0020-1693

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✦ Synopsis

The reaction of iron cyclopentadienyldicarbonyl halides with some vicinal triazole salts was investigated. It has been shown that these reactions yield isomeric complexes of triazoles. These complexes undergo isomeric rearrangement on heating in acid and neutral media. The coordinated triazoles contain two vacant basic centers. Therefore they participate in reactions with acids. H-bond formation and proton transfer reactions have been investigated for these complexes.

πŸ“œ SIMILAR VOLUMES

Iron cyclopentadienylcarbonyl complexes
Iron cyclopentadienylcarbonyl complexes with azoles. I. Complexes of imidazoles and vicinal triazoles
✍ A.N. Nesmeyanov; Yu.A. Belousov; V.N. Babin; O.G. Aleksandrov; Yu.T. Struchkov; πŸ“‚ Article πŸ“… 1977 πŸ› Elsevier Science 🌐 English βš– 751 KB

## The reactions of halides, a-CsHSFe(CO)?X (X = Cl, Br, I), with sodium salts of some triazoles and imidazoles yield compounds of the composition n-C5-HsFe(COJ2L (L = heterocycle moiety). These complexes react with acids and complex anions in water to form the salts [n-C,H,Fe(CO),LHJ' A-(A-= anion)