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Iron-cyclam complexes as catalysts for the epoxidation of olefins by 30% aqueous hydrogen peroxide in acetonitrile and methanol

✍ Scribed by Nam, Wonwoo; Ho, Raymond; Valentine, Joan Selverstone


Book ID
120242992
Publisher
American Chemical Society
Year
1991
Tongue
English
Weight
817 KB
Volume
113
Category
Article
ISSN
0002-7863

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A great variety of olefinic substrates having aromatic, carbocyclic and aliphatic olefins are effectively and selectively oxidized with oxygen-rich molybdenum(VI) complexes, namely 5 and [PPh 4 ][Mo(O) 3 -(QO)] 6 (QOH = 8-quinolinol) as catalyst, NaHCO 3 as co-catalyst and H 2 O 2 as the terminal o