Iron-Catalyzed Oxidation of Thioethers by Iodosylarenes: Stereoselectivity and Reaction Mechanism
✍ Scribed by Konstantin P. Bryliakov; Evgenii P. Talsi
- Publisher
- John Wiley and Sons
- Year
- 2007
- Tongue
- English
- Weight
- 124 KB
- Volume
- 13
- Category
- Article
- ISSN
- 0947-6539
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## Abstract The acid catalyzed addition of water to ethylthioethyne has been studied in aqueous solution. The reaction is general acid catalyzed and it is faster in H~2~O than in D~2~O. Substitution of a tertiary butyl group for the ethyl group results in a rate enhancement. The entropies of activa
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