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Iron-Catalyzed Olefin Epoxidation in the Presence of Acetic Acid: Insights into the Nature of the Metal-Based Oxidant

✍ Scribed by Mas-Ballesté, Rubén; Que, Lawrence

Book ID
120353304
Publisher
American Chemical Society
Year
2007
Tongue
English
Weight
247 KB
Volume
129
Category
Article
ISSN
0002-7863

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In situ Formation of Peracetic Acid in Iron-Catalyzed Epoxidations by Hydrogen Peroxide in the Presence of Acetic Acid
✍ Megumi Fujita; Lawrence Que Jr. 📂 Article 📅 2004 🏛 John Wiley and Sons 🌐 English ⚖ 102 KB 👁 2 views

## Abstract Iron complexes (tpa)Fe(OTf)~2~ (1) and (bpmen)Fe(OTf)~2~ (2) [tpa=tris‐(2‐pyridylmethyl)amine; bpmen=__N,N′__‐bis‐(2‐pyridylmethyl)‐__N,N′‐__dimethyl‐1,2‐ethylenediamine] were found to catalyze the __in situ__ formation of AcOOH from H~2~O~2~ and AcOH in the course of olefin oxidations.