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Iron-Catalyzed Direct Synthesis of Imines from Amines or Alcohols and Amines via Aerobic Oxidative Reactions under Air

✍ Scribed by Zhang, Erlei; Tian, Haiwen; Xu, Sendong; Yu, Xiaochun; Xu, Qing

Book ID
120336550
Publisher
American Chemical Society
Year
2013
Tongue
English
Weight
327 KB
Volume
15
Category
Article
ISSN
1523-7060

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By ligand, TEMPO, and base screening, we developed a mild and green one-pot imine synthesis from alcohols and amines via a low-loading palladium-catalyzed tandem aerobic alcohol oxidation-dehydrative condensation reaction that can be readily carried out in open air at room temperature.

ChemInform Abstract: Direct and Mild Pal
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## Abstract By ligand, (TEMPO) and base screening a mild one pot imine synthesis from benzylic alcohols (I) and amines (II) via a Pd‐catalyzed tandem aerobic alcohol oxidation/dehydrative condensation sequence is developed.